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EDUCATION: GLOBAL METHANE INVENTORY

Inventory of Methane Emissions

1. The Methane Inventory Project

The scientific objectives of this research are to understand the global methane cycle, including how its sources and sinks have changed over the last ten years, how they might change in future decades, and what the implications are for climate.

2. Project Background

The International Global Atmospheric Chemistry (IGAC) project of IGBP (International Geosphere-Biosphere Programme) initiated the Global Emissions Inventory Activity (GEIA) in 1991. The purpose of IGAC is to measure, understand, and predict changes in global atmospheric chemistry (Graedel, 1994); the purpose of GEIA is to develop global, widely recognized emissions inventories of a variety of gases and particles in support of atmospheric chemistry models. The modeling community recognized the advantages of supporting a consensus data effort such as GEIA. For example, providing a standardized, authoritative dataset of methane emissions for use in atmospheric chemistry models means that differences among results of various models come from differences among the models themselves and not from a combination of different models and different input data. On a practical level, standardized datasets reduce the effort spent by individual research groups to develop distributions of emissions for their modeling work.

Atmospheric concentrations of methane, as well as its sources and their seasonal and spatial distribution, are reasonably well known. datasets of methane emissions were produced prior to GEIA by Elaine Matthews, Inez Fung, and Jean Lerner, at the NASA Goddard Institute for Space Studies (GISS). Some of these datasets are available via data centers, institutional anonymous FTP, and the World Wide Web. Major limitations to distribution of the complete inventory are:

  1. lack of standardization and adequate documentation of the source fields.
  2. data on several sources, such as rice cultivation and energy, reflect the conditions and knowledge base of the mid-1980s.

In 1993, GEIA's methane working group presented recommendations for estimating global inventories of the following natural and anthropogenic methane sources: coal mining and processing, natural gas production, transmission, and distribution, landfills, rice cultivation, wetlands and animals. (Emissions from biomass burning are the subject of another GEIA activity (BIBEX)). These recommendations make use of existing datasets where possible, and include specifics about methodologies, uncertainties, and data availability.

3. Project Objectives

The overall objective of this research is to compile and distribute a current, complete, and internationally-recognized inventory of methane sources and associated emissions. This research has the following components:

  1. update the previous GISS datasets, which reflect 1984, to the GEIA reference year of 1990 using the methodologies of GEIA's Methane Working Group and of IPCC.
  2. formally document and publish these datasets and make the complete suite of methane emission data available to the research community. Establishing this formal process not only sets that stage for future updates but provides for historical reconstructions of methane emissions which have received little attention.

4. The Project

4.1 Methane Emission from Rice Cultivation

The focus of the 1996 summer project was on estimating global methane emission from wetland rice cultivation in 1990 using the default IPCC methodology for that source.

Methodology. The IPCC methodology was developed according to the concept that ideal conditions for methane emission from rice cultivation are those in which flooding is continuous throughout the growing season for the rice. Such continuous flooding is considered to occur only under artificially irrigated conditions; rainfed rice cultivation is prevalent is some countries but under these conditions, fields typically are subject to intermittent flooding during the growing season. Dryland rice produces no methane. Based on measurements of methane emission from rice fields, the IPCC methodology assumes that methane emission from rice under ideal conditions (continuous flooding under irrigation) is 20 grams of methane per square meter per year (g CH4/m2/yr) and that fields managed under other water regimes (rainfed) produce methane at lower rates. In the calculation, emission factors are associated with water regimes and define the value used to "adjust" the maximum emission value of 20 g CH4/m2/yr. The emission factor for irrigated fields is 1.0 × 20 g CH4/m2/yr. For rainfed rice fields the factor is 0.8 × 20 g CH4/m2/yr if under continuous flooding, 0.4 if under intermittent flooding, and 0.6 if the flooding regime is not specified (undifferentiated).

To calculate the total methane emissions from an area, the emissions produced under each water regime are calculated and summed. The total is multiplied by 1 #215;105 to convert from 107 g to 1012 g (teragrams).

Methane Total = [ (Methane from Irrigated fields [Mi])
+ (Methane from Undifferentiated Rainfed fields [Mru])
+ (Methane from Rainfed fields under Continuous Flooding [Mrc])
+ (Methane from Rainfed fields under Intermittent Flooding [Mri]) ] × 1×105

The methane emission for each water regime is found by taking the product of the Total Harvested Area [At], the % Area Irrigated [Ai] or Rainfed (undifferentiated [Aru] or continuous flooding [Arc] or intermittent flooding [Ari]), the appropriate emission factor for each water regime (Fi, Fru, Frc, Fri ), and the IPCC default emission value of 20 g CH4/m2/yr. The total is multiplied by 1×105 to convert to teragrams.

Mtotal = [(At × Ai × .01 × Fi × 20 g CH4/m2/yr)
(At × Aru × .01 × Fru × 20 g CH4/m2/yr)
(At × Arc × .01 × Frc × 20 g CH4/m2/yr)
(At × Ari × .01 × Fri × 20 g CH4/m2/yr)] × (1×105)

(Note: The factor of .01 in the calculation is to convert the number for area irrigated or rainfed into a percentage.)

Mtotal = total methane emission in Tg CH4/year
At = total harvested rice area in thousands of hectares (103 ha or 107m2)
Ad = fraction (%) of area dry
Ai = fraction (%) of area irrigated - under continuous flooding
Fi = methane emission factor for irrigated fields - continuous flooding = 1.0
Aru = fraction (%) of area rainfed (undifferentiated) - flooding regime not specified
Fru = methane emission for rainfed (undifferentiated) fields-flooding regime not specified = 0.6
Arc = fraction (%) of area rainfed (continuous) - under continuous flooding
Frc = methane emission for rainfed (continuous) fields - under continuous flooding = 0.8
Ari = fraction (%) of area rainfed (intermittent) - under intermittent flooding
Fri = methane emission for rainfed (intermittent) fields - under intermittent flooding = 0.4
1×105 = multiply results by 1×105 to convert from 107g to 1012 g or Tg

An example is shown below:

Country Area (107 m2) % Dry % Irrigated × .01 % Rainfed × .01
North Korea 1200 13% 67% 20%

Methane emissions from continuously flooded fields:

Mi = At × Ai × .01 × Fi × 20 g CH4/m2
    1200 × 67 × .01 × 1 × 20g CH4/m2 = 16080×109 g × 105 = .16 Tg

Methane emissions from undifferentiated rainfed fields:

Mru = At × Aru × .01 × Fru × 20g CH4/m2
    1200 × 20 × .01 × .6 × 20g CH4/m2 = 2880×109 g × 105 = .03 Tg

Total Emissions = .19 Tg:

The inventory was accomplished by obtaining information on rice-harvest areas for all rice-producing countries of the world reflecting the GEIA reference year of 1990. The country data on harvested rice areas were obtained from the 1990 UN Food and Agriculture Production Yearbook (FAO, 1990). Subnational statistics for harvested rice areas were also obtained for the United States, India, China, and Brazil from statistical yearbooks. Using geographic information on locations of rice-cultivation from a land-use dataset already developed (Matthews, 1991) and following the default IPCC methodology for estimating emission from this source, a global inventory of methane emission from rice cultivation was developed. Additional regional data was obtained from statistical yearbooks by country.

Results and Discussion. The 1990 emission of methane from rice was calculated to be 19.1 Tg. A regional summary of the results is shown in Table 3-1. Figure 3-1 shows the global distribution of results in g CH4/m2/yr. The overwhelming proportion of the total area (90%) and emissions (95%) comes from East Asia. Mean rates of methane emission for Africa, South and Central America are one third to one half the maximum rate of 20 g CH4/m2/yr. Fields in East Asia emit at a rate of about 14 g CH4/m2/yr, 75% of the maximum. Rice fields in the remaining regions are almost exclusively irrigated and therefore produce methane at the maximum rate.

1990 Methane Emission from Rice
Figure 3-1: Methane emission from rice cultivation based on IPCC methodology.
(Click on image for a larger version).

Table 3-1. Summary of global methane emissions from rice for 1990 based on IPCC methodology.
  Mi Mru Mrc Mri Mtotal-g Mtotal-Tg Mmean
  Methane
Irrigated
(109 g)
Methane
Rainfed
Undifferentiated
(109 g)
Methane
Rainfed
Continuous
(109 g)
Methane
Rainfed
Intermittent
(109 g)
Methane
Total
(109 g)
Methane
Total
(1012 g = Tg)
Methane
mean
(g/m2/yr)
East Asia 131,468 15,445 29 2,195 2,379 20,048 20.0 15.2
Africa 6,470 307 50 4 69 430 0.4 6.6
South America 5,279 346 29 0 23 398 0.4 7.5
North America 1,216 231 0 0 0 231 0.2 19.0
Former CPEs - Europe 690 138 0 0 0 138 0.1 20.0
West Asia 650 130 0 0 0 130 0.1 20.0
Central Amer. / Caribbean 560 57 0 0 0 57 0.1 10.2
Europe 375 75 0 0 0 75 0.1 20.0
Oceania 132 25 1 0 0 26 0.0 19.5
Global Total 146,840 16,754 109 2,199 2,471 21,533 21.5 14.7
NOTES:
irrig = irrigated
rain = rainfed (less complete flooding)
undifferentiated = rainfed, undifferentiated flooding regime
continuous = rainfed, continuous flooding
intermittent = rainfed, intermittent flooding
109 g = billions of grams
1012 grams = 103 × 109 = Teragrams = trillions of grams

The global total of 19.4 Tg is lower than any other published estimates (IPCC, 1995). Since there is substantial uncertainty about the total amount of methane emitted from rice cultivation, this unexpectedly low value could be correct. However, the appropriate comparison is between the calculated emission rates for rice fields in various countries and field measurements of emission rates in major rice-growing countries (IPCC, 1995). Crude averages for methane emission, from a set of field measurements for China and for India, are about 60 and 25 g CH4/m2/yr, respectively (IPCC, 1995). Using the IPCC methodology, we calculated country means of 19 and 11 g CH4/m2/yr for China and India, respectively. Therefore, the measurement means for China are about three times the value calculated using the IPCC methods. In addition, measurements for India indicate that actual field emissions may be 25% higher than the maximum possible using the IPCC methods (and about 20 g CH4/m2/yr) and 2.5 times the mean value calculated in the present study for India using the IPCC methods.

The latest IPCC methodology, which was used in this study, is a simplified version of an early one which had included data on crop growing seasons - number of days crops were growing, the months in which crops were grown, and number of crops grown in a year. However, since the GEIA inventories are designed as input for modeling of atmospheric chemistry, the seasonal cycle of emissions must be evaluated. We plan to include seasonal cropping calendars (Matthews et al, 1991) in our next calculation of methane emission from rice cultivation.

4.2 Methane Emission from Landfills

Research at Mott Hall Junior High School 1996-1997

The topic of greenhouse effect and global warming is part of the 8th grade Earth science curriculum at Mott Hall Intermediate School and is taught within the context of the nature of solar energy and its interaction with the Earth's atmosphere and surface, and atmospheric chemical processes.

The continuation of the project during the 1996-97 schoolyear built on the research carried out at GISS during the summer and extended the summer's demonstration product to encompass an additional methane source: landfills. During the 1996-97 schoolyear, 10 students and the instructor worked on developing an inventory for 1990 contributions of landfills to emission of methane to the atmosphere. They began with North America and the Caribbean where data are prevalent. The IPCC methodologies provide default values for several variables needed in the estimate including per capita refuse production, fraction of refuse placed in landfills, fraction of refuse decomposing anaerobically, methane potential of waste, and level of methane recovery. However, the students needed population statistics in order to estimate the total amount of waste generated, as well as to develop the geographic distribution of methane emission ultimately required by atmospheric chemistry modelers. Working as a team, with one student as a facilitator, each student selected several states/provinces/countries and compiled 1990 population statistics on the following: population of cities < 50,000; city latitudes/longitudes; and total, urban and rural populations for states of the United States, provinces of Canada, and other countries. Each student contributed his/her population statistics to the effort, and the team carried out the IPCC default calculation of methane emissions from landfills in North America and the Caribbean. The students worked together to produce a report and a science fair poster on their research (the Mott Hall science fair took place on 28 May, 1997). The report/posters describe the scientific background for the udy of methane emissions, sources of data, an overview of methane sources, details of the IPCC methodology and how it was implemented, sources of population data, and results of the study.

Methodology. The IPCC methodology for calculating methane emissions from landfills was based on estimates of the factors influencing methane production in solid waste. Foremost among these is the degradable organic carbon (DOC) content of the waste. The percent of DOC is based on the composition of the waste. Since the composition can vary widely especially between developed and developing countries, data on the amount and composition of solid waste from various regions were collected. From this, default values for the per capita production of solid waste, the fraction to landfill and the fraction of DOC may be calculated for various countries. Where data for specific countries are sparse, assumptions are made based on regional data available.

Calculating methane emissions from landfills requires data on the urban and rural population and the per capita solid waste production of a country from which the total amount of municipal solid waste (MSW) can be calculated. Methane emissions can then be calculated by applying the IPCC default values for the fraction of the total MSW to landfill and the fraction of DOC in that landfill that undergoes anaerobic decay and multiplying that by the methane potential.

This procedure is as follows:

Step 1 - Calculate the Total Municipal Solid Waste in Tg (109g)

Total Municipal Solid
Waste (MSW) generated
= (Urban Population [Pu] × Urban MSW generated Factor [Fu] in kg/capita/day × 365 days)
+ (Rural Population [Pr] × Rural MSW generated Factor [Fr] in kg/capita/day × 365 days)

divided by 1×106 to convert 103 kg to 1012 g = Terragrams.

MSWt = [ (Pu × Fu × 365) + (Pr × Fr × 365) ] / (1×106)

Step 2 - Calculate the methane emissions in Tg 1012g)

Methane Emission = Total MSW Generated (from part 1) × Fraction Going to Landfill [Fl] × Fraction Undergoing Anaerobic Decay [Fa] × Methane Potential Factor [Fmp] × .001372
M = MSWt × Fl × Fa × Fmp × .001372
M = Methane emission in tg (1012 g)
Pu = Urban Population
Fu = Urban MSW factor kg/cap/d
Pr = Rural Population
Fr = Rural MSW factor kg/cap/d
MSWt = Total MSW tg/yr
Fl = Fraction to landfill
Fa = Fraction undergoing Anaerobic decay
Fmp = Methane potential factor (l/kg)
.001372 = Conversion factor to convert l/kg to tg.

Example:

State Urban Population
(in 1000s)
Fu Rural Population
(in 1000s)
Fr Fl Fa Fmp
Alabama 2440 1.9 1601 1.9 0.7 1.0 57

Step 1 - Calculate the Total Municipal Solid Waste in Tg (109 g)

MSWt = [ (Pu × Fu × 365) + (Pr × Fr × 365) ] / (1×106)

MSWt = [ (2440 × 1.9 × 365) + (1601 × 1.9 × 365) ] / (1×106) = 2.802 Tg/yr

Step 2 - Calculate the methane emissions in Tg (109 g)

M = MSWt × Fl × Fa × Fmp × .001372

M = 2.802 × 0.7 × 1.0 × 57 × .001372 = 0.153 Tg/yr

Results and Discussion. Methane emissions from landfills in the United States (50 states) for the 1990 reference year were calculated to be 9.4 Tg/yr (Table 3-2). This represents about 30% of the global total. Since the methodology is based on population, the five most populous states, California, New York, Texas, Florida, and Pennsylvania, (Figure 3-2) account for 36% of the population and 36% of the methane production.

Table 3-2. United States methane emissions for 1990 based on IPCC methodology.
States Total Pop.
1000s
Urban Pop.
1000s
Rural Pop.
1000s
Total
MSW tg/yr
Methane
Emission tg/yr
PT PU PR MSWT M
California 29,760 27,571 2,189 20.639 1.13
New York 17,990 15,164 2,826 12.476 0.68
Texas 16,987 13,635 3,352 11.780 0.64
Florida 12,938 10,967 1,971 8.973 0.49
Pennsylvania 11,882 8,188 3,694 8.240 0.45
Illinois 11,431 9,669 1,762 7.927 0.43
Ohio 10,847 8,039 2,808 7.522 0.41
Michigan 9,395 6,556 2,839 6.515 0.36
New Jersey 7,730 6,910 820 5.361 0.29
North Carolina 6,629 3,338 3,291 4.597 0.25
Georgia 6,478 4,097 2,381 4.492 0.25
Virginia 6,187 4,293 1,894 4.291 0.23
Massachusetts 6,016 5,070 946 4.172 0.23
Indiana 5,544 3,598 1,946 3.845 0.21
Missouri 5,117 3,516 1,601 3.549 0.19
Wisconsin 4,892 3,212 1,680 3.393 0.19
Tennessee 4,877 2,970 1,907 3.382 0.19
Washington 4,867 3,718 1,149 3.375 0.18
Maryland 4,781 3,888 893 3.316 0.18
Minnesota 4,375 3,056 1,319 3.034 0.17
Lousiana 4,217 2,872 1,345 2.924 0.16
Alabama 4,041 2,440 1,601 2.802 0.15
Kentucky 3,685 1,910 1,775 2.556 0.14
Arizona 3,665 3,207 458 2.542 0.14
South Carolina 3,487 1,905 1,582 2.418 0.13
Colorado 3,294 2,716 578 2.284 0.13
Connecticut 3,287 2,602 685 2.280 0.12
Oklahoma 3,146 2,130 1,016 2.182 0.12
Oregon 2,842 2,003 839 1.971 0.11
Iowa 2,777 1,683 1,094 1.926 0.11
Mississippi 2,573 1,211 1,362 1.784 0.10
Kansas 2,478 1,713 765 1.718 0.09
Arkansas 2,351 1,258 1,093 1.630 0.09
West Virginia 1,793 648 1,145 1.243 0.07
Utah 1,723 499 1,224 1.195 0.07
Nebraska 1,578 1,044 534 1.094 0.06
New Mexico 1,515 1,106 409 1.051 0.06
Maine 1,228 548 680 0.852 0.05
Nevada 1,202 1,061 141 0.834 0.05
New Hampshire 1,109 566 543 0.769 0.04
Hawaii 1,108 986 122 0.768 0.04
Idaho 1,007 578 429 0.698 0.04
Rhode Island 1,003 863 140 0.696 0.04
Montana 799 420 379 0.554 0.03
South Dakota 696 348 348 0.483 0.03
Delaware 666 487 179 0.462 0.03
North Dakota 639 340 299 0.443 0.02
Vermont 563 181 382 0.390 0.02
Alaska 550 371 179 0.381 0.02
Wyoming 454 295 159 0.315 0.02
US Total 0 185,446 62,753 172.126 9.42

The methodology used allows for a simple calculation of methane emissions from landfills globally. However, there are a number of uncertainties which affect these estimates. The time between the placement of waste and the production of methane, and the oxidation of methane as it diffuses to the surface of the landfill remain substantial uncertainties. Obtaining more data on the composition and amount of MSW, especially in developing countries, could make better estimates of methane emissions. This is a subject further discussed in the Student Involvement component.

4.3 Inventory of Animals and Associated Methane Emissions

During the summer program of 1997, the student and faculty member of the team are collecting 1990 data on animal populations by country, and by political bdivision for large countries. Animals to be included are: dairy and beef cattle, sheep, goats, pigs, water buffalo, and camels. When the data compilation is completed, the global methane emission from animals will be calculated using the IPCC default methodology; geographic distribution of the animal densities and associated emissions will be obtained using previously developed global, 1 degree resolution datasets of locations of animals (Lerner et al., 1988) in conjunction with the emissions from IPCC for countries.

USA.gov

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